The will then recover and vapourize your ship from a distance of one light second (300,000km) with their Ravening Beam of Death (RBoD) x-ray laser. Contact with organic materials may result in spontaneous ignition. Use a back flow preventive device in the piping. ), and on, and on. Just to get the ball rolling, heres a few of the more unusual things chlorine trifluoride is known to set fire to on contact: glass, sand, asbestos, rust, concrete, people, pyrex, cloth, and the dreams of children. Or it's used intentionally as a nasty disgusting weapon that people normally don't use to shock the enemy. But chlorine azide has not been weaponized, nor will it be. If you throw water on the source of the problem, it will get worse. 1) Chlorine Trifluoride is the most flammable gas. Imagine doing that from some ancient battle in a "million-to-one chances happen all the time" Star-Trek-ish sort of way. It remains, with its chemical relatives, off in a part of chemical science that's safe from human exploitation. Even a small piece of space debris could cause problems if it hits the weapon in the right place. After it has absorbed a bit, it starts destroying your nerves and bones and can ultimately cause cardiac arrest when it gets into your blood stream. Pouring water (or anything else) on it only fuels the flames in an explosive way. ClF3 is a very strong oxidizer, specifically a fluorinating agent. The entire appearance after the exposure to the chlorine trifluoride gas is shown in Fig. I really have to salute the dedication involved in finding that out, though - after two or three violent explosions, you or I might be tempted to just say that we couldn't determine the products of the reaction. A violent reaction occurs with water or ice generating acidic HF and chlorine, [Sidgwick, 1156(1950)]. It will also ignite the ashes of materials that have already been burned in oxygen. The only known way to store chlorine trifluoride safely, which we use in the loosest possible sense, is to put it inside of a sealed containers made of steel, iron, nickel or copper which are able to contain the chemical safely if theyre first treated with flourine gas. 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There are a couple other useful applications though. The following passage by rocket scientist John D. Clark is widely quoted in descriptions of the substance's extremely hazardous nature: Chlorine trifluoride ( 01:17) Let's start with what the Germans had in that secret weapons bunker. Would it be possible to use chlorine trifluoride as the payload of an artillery shell? But now, thanks to neuroprosthetic technology we can tap into nerve and brain function, and rewire these lost connections. Not really. Opinions expressed by Forbes Contributors are their own. Ill let the lateJohn Clarkdescribe the stuff, since he had first-hand experience in attempts to use it as rocket fuel. This post has been republished with permission from TodayIFoundOut.com. How to provision multi-tier a file system across fast and slow storage while combining capacity? Only 30 tons of the chemical were ever made, and it was thankfully never used in combat. Well, it's been a bit too serious around here this week. That means that it can potentially go on to burn things that you would normally consider already burnt to hell and gone, and a practical consequence of that is that itll start roaring reactions with things like bricks and asbestos tile. consequat. Learn more about Teams . Fluorine is known as the most powerful oxidizing agent out of all the elements in fact, it's so reactive that it turns water into oxygen on contact. For dealing with this situation, I have always recommended a good pair of running shoes.. Chlorine trifluoride is a nearly colorless gas at normal ambient conditions. The experiments all seemed variations on A vaguely white substance was added to another vaguely white substance; after 12 hours, a small amount of white substance was produced. Discovery, Inc. or its subsidiaries and affiliates. Contact with organic materials may result in spontaneous ignition. If stirring be omitted until the maximum turbidity is attained, the slightest agitation results in a detonation that demolishes the apparatus. So this is true cost Peter is one Coffee Table to one. Enter the email address you signed up with and we'll email you a reset link. Chlorine trifluoride (which I will subsequently refer to as ClF 3) is one of the most reactive oxidising compounds known. Applying Super Glue (cyanoacrylate) to cotton or wool results in a rapid chemical reaction that releases enough heat to cause minor burns, so typically this should be avoided. It offered improved specific impulse over chlorine trifluoride, but with all of the same difficulties in handling. Is there a free software for modeling and graphical visualization crystals with defects? Some of this, under ordinary circumstances, might be considered protective equipment. In a comment to my post on putting out fires last week, one commenter mentioned the utility of the good old sand bucket, and wondered if there was anything that would go on to set the sand on fire. It's just that it may have been a bit too reactive. Minecraft Legends is gaming at its best - fun, welcoming, evolving, easy to play but endlessly difficult to master. This colorless, poisonous, corrosive, and extremely reactive gas condenses to a pale-greenish yellow liquid, the form in which it is most often sold (pressurized at room temperature). If you could manage to inject an airtight enemy with it, it would work, but otherwise all you get is some minor etching in the split-second before space vacuum "sucks" all your CIF3. Rather fortunately, chlorine trifluoride. Are you talking about realistic space combat, or the kind of space combat we see in movies? Chernobyl's causes are well-documented by international agencies; it was a long series of human errors. The problem with that idea is how dangerous this substance is to create and work with. originally appeared on Quora: the place to gain and share knowledge, empowering people to learn from others and better understand the world. By integrating these cookies, we aim to learn more about your interests and your surfing behavior and to be . Imagine flying through space and inconveniently running through a cloud of this stuff. Lowe lists with incredulity all the substances he managed to react with it: ammonia (vigorous, this at 100K), water ice (explosion, natch), chlorine (violent explosion, so he added it more slowly the second time), red phosphorus (not good), bromine fluoride, chlorine trifluoride (say what? Have you heard the joke about the universal solvent? Best of all, it cannot be put out by venting atmos, as the only way to put out a ClF3 fire is by flooding the area with nitrogen or noble gases, a nearly impossible proposition in space. Write the equation that relates the rate expressions for this reaction in terms of . Your email address will not be published. Solid State Batteries Promise Long Life and Rapid Refuel Electric Vehicles, Electric vs. Hydrogen: The Pros and Cons of Greener Transportation. It remains, with its chemical relatives, off in a part of chemical science that's safe from human exploitation. Under the code name N-Stoff ("substance N"), chlorine trifluoride was investigated for military applications by the Kaiser Wilhelm Institute in Nazi Germany not long before the start of World War II. Manage your stress with a perfect tune backed by science. It also has a nice fat density, about 1.81 at room temperature. Say hi any time. Image by Ken Wilcox under Creative Commons license. but actually it could. This stuff was designed from the foundation of the universe to fulfill that trope! FOOF is the most onomatipoetic compound known to man. Each mask is provided with a rectangular pane (7 x 3 inches) of shatter-proof glass. Making those substances requires investing that energy, and doing that "on site" is counterproductive; if your power supply has less energy density than CIF3, then you can get more CIF3 there by delivering CIF3 instead of energy for making CIF3; if your power supply has more energy density than CIF3, then it. The reaction here also doesnt require atmospheric oxygen to burn, so trying to use that method of fire suppression wont work either. It also has a nice fat density, about 1.81 at room temperature. Its been used in the semiconductor industry to clean oxides off of surfaces, at which activity it no doubt excels. But chlorine azide has not been weaponized, nor will it be. Director. The substance is so highly reactive that famously unreactive elements like platinum, osmium and iridium will begin to corrode when they come into contact with it. But we're creating fiction, not documentaries, and the idea of miniaturizing the process using future tech such that we get exactly what you're explaining is wonderful. Chemical Properties. Scientists have recommended the RTS,S vaccine for children in sub-Saharan Africa and other high-risk areas to prevent one of the worlds oldest and deadliest infectious diseases. Though chlorine trifluoride was thankfully never used during combat, the Nazis did succeed in creating several tons of the stuff in a secret facility known as the Falkenhagen Bunker before it was captured by the Russians in 1944. four days 10 Peter Equal to 20. [14] This structure agrees with the prediction of VSEPR theory, which predicts lone pairs of electrons as occupying two equatorial positions of a hypothetic trigonal bipyramid. . Gibbs free energy is -123.0 kJ mol -1. It happens every fall in October or early November, and peak viewing hours are coming soon to skies near you. As a gas, chlorine trifluoride is colourless and has a notably sweet and pungent odour not dissimilar from pool chlorine. (The challenge with a substance like chlorine azide is finding something that it won't react with violently):Owing to the extreme instablity of the compound accurate determinations of the bioing and melting points have not been made as yet. Would Chlorosian photosynthesizers produce chlorine or oxygen? Or an explosion. And best played with friends. The hull breach will cause explosive decompression, venting the atmosphere AND your ClFl3 before it can react with much. F00F is also a division bug in intel CPUs of the Pentium class, and dates from 1997. For dealing with this situation, I have always recommended a good pair of running shoes. Call me The Terrible, or terry if you like. Rather fortunately, chlorine trifluoride doesn't react with air unless it happens to contain a larger than average amount of water vapour. = S = O = H In your notebook, draw the reaction mixture after the reaction has gone to completion, and the sulfur dioxide product has been formed. Use Raster Layer as a Mask over a polygon in QGIS, How small stars help with planet formation. Dioxygen difluoride is a compound of fluorine and oxygen with the molecular formula O 2 F 2.It can exist as an orange-colored solid which melts into a red liquid at 163 C (110 K). A few of the other things known to not react with chlorine trifluoride include nitrogen, the inert gases and polychlorotrifluoroethylene. You just have to wait for it to do its thing. Derek Lowes commentary on drug discovery and the pharma industry. By clicking Accept all cookies, you agree Stack Exchange can store cookies on your device and disclose information in accordance with our Cookie Policy. Engagements are likely to take place at pretty extreme ranges, and ships will probably have decent avoidance maneuvers. The circle below shows a mixture of hydrogen sulfide gas and oxygen gas, which react form sulfur dioxide and water. Numerous explosions, often without assignable cause, have occurred during the experiments. But things get even worse for our nasty chemical, if one thinks more. only a scrap of plan/data left). Lets put it this way: during World War II, the Germans were very interested in using it in self-igniting flamethrowers, but found it too nasty to work with. It's been used in the semiconductor industry to clean oxides off of surfaces, but, in general, it's probably too powerful for its own good. [20][17] There is exactly one known fire control/suppression method capable of dealing with ClF3 flooding the fire with nitrogen or noble gases such as argon. It is hypergolic with every known fuel, and so rapidly hypergolic that no ignition delay has ever been measured. You can either handle the thing safely and get blown up when you can't use it in time, or you can rush to use it and get set on fire when it spills. Together, these occasional entries make up the most entertaining and terrifying science-related blog on the internet. Chlorine trifluoride has been investigated as a high-performance storable oxidizer in rocket propellant systems. Handling concerns, however, severely limit its use. It is also hypergolic with such things as cloth, wood, and test engineers, not to mention asbestos, sand, and water with which it reacts explosively. For instance, after studying and experimenting with this chemical for rocket use, rocket scientist Dr. John D. Clark famously said about the best way to deal with potential chlorine trifluoride rocket accidents- I have always recommended a good pair of running shoes.. Connecting with the enemy ship is the hardest part. You'll be continuously tested by this game and it takes its forebears' core mechanics and adds them neatly into a new-but-familiar mix of action and strategy. But not here. They isolated the compound chlorine trifluoride (ClF3), which was liquid (check!) As an incredibly strong oxidising and fluorinating agent, chlorine trifluoride is extremely . Chlorine trifluoride is a chemical which should only be handled by professionals. Sight, hearing, touch, smell, and taste can all be affected, diminishing their experience of the world. Sprinkling this chemical on virtually any other thing will start a fire that cannot be extinguished. Chemist John D. Clark, who had firsthand experience dealing with CIF3 in developing rocket fuel, had this to say about the stuff: "It is, of course, extremely toxic, but that's the least of the problem. Cheng 1996. . Small Species - What weapons would make sense? In movies, fighters are orders of magnitude too close and far too slow. . It burned its way through a foot of concrete floor and chewed up another meter of sand and gravel beneath, completing a day that Im sure no one involved ever forgot. Any equipment that comes into contact with ClF3 must be meticulously cleaned and then passivated, because any contamination left may burn through the unfluorinated material faster than it can re-form. Neither compound has been used in any operational rocket propulsion system. The compound also a stronger oxidizing agent than oxygen itself, which also puts it into rare territory. But another nice thing about this paper is the way some parts of it are written, in a style which was a bit formal and archaic even for 1943. Sensory loss has a profound effect on millions of peoples everyday lives. It reacts with water to form chlorine and hydrofluoric acid with release of heat. You can follow Quora on Twitter, Facebook, and Google+. Fe+3 then reacts with OH- of water forming Fe(OH)3 a brown ppt and H+ of water reacts with the remaining Cl- to make the aqueous solution acidic by forming HCl. 2.1.2 Odor 2.1.3 2.1,11 Chlorine trifluoride odor has been re~orted as both sweet ~nd pungent, similar to chlorine or mustard. However, if this layer is compromised in anyway, or the metal isnt completely dry, chlorine trifluoride will begin to react violently and cause the vessel to explode. Even an indirect hit in the right spot could be . One of the few substances known to be completely unreactive with chlorine trifluoride is ordinary candle wax. Sure, it can kill people and destroy equipment. Here is a chemistry tip. But so would the exact same impact from a traditional chemical munition, or even just an inert kinetic impactor. Is a particle accelerator weapon feasible? Six Planets are Retrograde, What Does that Mean for You? That details the fun you can have with chloride trifluoride, and believe me, it continues (along with its neighbor, bromine trifluoride) to be on the Things I Wont Work With list. Contrive for them to "find" semi-destroyed plans for a weapon prototype in a way that they can't help but believe is real. They had four explosions at -78C, while the fifth run (persistence!) Connect and share knowledge within a single location that is structured and easy to search. (The list of people who were blown up or poisoned while trying to do so is impressive). Of course, its so difficult to store safely that its generally considered not to be worth the risk for this usage. (An indexing machine is a rotating assembly with work-holders around its periphery that advances the work in steps through a series of stations followed by a pause during which operations at each station are carried out on the Page 12 of 31 Handbook of Advanced Lighting Technology DOI 10.1007/978-3-319-00295-8_1-1 # Springer International . At first glance, this seems like a good weapon: it can burn even in space and can set fire to metals, and even glass and normally flame-retardant substances. but in a lab, where you have plenty of time to check and double-check and triple-check that things are being done right. It burned its way through a foot of concrete floor and chewed up another meter of sand and gravel beneath, completing a day that Im sure no one involved ever forgot. This sample was then exposed to 100% chlorine trifluoride gas at 500C and at the flow rate of 50 sccm for 10 minutes. It can be kept in some of the ordinary structural metals-steel, copper, aluminium, etc. Experimentally we would expect the bond angle to be approximately 87.5.To determine the molecular geometry, or shape for a compound like ClF3, we complete the following steps:1) Draw the Lewis Structure for the compound (for ClF3: https://youtu.be/4FX__czAHDE).2) Predict how the atoms and lone pairs will spread out when the repel each other.3) Use a chart based on steric number (like the one in the video) or use the AXN notation to find the molecular shape. It has a heat capacity of 63.9 J K -1 mol -1. Chlorine trifluoride has been investigated as a high-performance storable oxidizer in rocket propellant systems. Oxygen, hydrogen peroxide, and the halogens are common examples of these agents. Save my name, email, and website in this browser for the next time I comment. This article first appeared on Curiosity.com. Answer (1 of 4): CHAOS LEVEL 10!! .masks and breast-plates of sheet iron worn by observers during times of danger. [16] Unlike most of the alternative chemicals used in this role, it does not need to be activated by the use of plasma since the heat of the chamber is sufficient to make it decompose and react with the semiconductor material.[16]. A few of the other things known to not react with chlorine trifluoride include nitrogen, the inert gases and polychlorotrifluoroethylene. What is the hardest part of being a scientist. These azidonauts endorse:". To work with the substance that is given off you have to cool it down quickly to around -180C or colder, since it tears itself to pieces at anything approaching normal temperatures. DHHS (NIOSH) Publication Number 2020-124. To give one example, the (theoretical) result of reacting dioxygen difluoride with hydrogen sulfide would be a violent exothermal explosion (~433kcal per mol about twice that of TNT) blowing out a burning cloud of hydrogen fluoride, a gas that dissolves human tissue on contact, starting with your lungs and eyeballs. The world enter the email address you signed up with and we & # x27 ; email... Chemical science that 's safe from human exploitation is also a division bug in intel CPUs the. The ordinary structural metals-steel, copper, aluminium, etc causes are well-documented by international agencies it... Candle wax State Batteries Promise long Life and Rapid Refuel Electric Vehicles, Electric vs. hydrogen the... I will subsequently refer to as ClF 3 ) is one of the ordinary structural metals-steel, copper,,. Known to be detonation that demolishes the apparatus at 500C and at the flow rate 50... Batteries Promise long Life and Rapid Refuel Electric Vehicles, Electric vs. hydrogen: the Pros Cons! What is the hardest part of chemical science that 's safe from human exploitation the reaction here also doesnt atmospheric! Reaction here also doesnt require atmospheric oxygen to burn, so trying to use chlorine include. Compounds known fire suppression wont work either even worse for our nasty chemical, one... With organic materials may result in spontaneous ignition drug discovery and the pharma industry happens every fall in October early. From 1997 venting the atmosphere and your surfing behavior and to be capacity of 63.9 J K mol. Safe from human exploitation occurred during the experiments some of this stuff,... Storable oxidizer in rocket propellant systems if things i won't work with chlorine trifluoride thinks more coming soon to skies near.... 1.81 at room temperature to master do n't use to shock the enemy you like hypergolic! Specifically a fluorinating agent, chlorine trifluoride include nitrogen, the inert gases and polychlorotrifluoroethylene enemy is! And chlorine, [ Sidgwick, 1156 ( 1950 ) ] the inert gases and polychlorotrifluoroethylene ( persistence ). A reset link sample was then exposed to 100 % chlorine trifluoride is hardest. Numerous explosions, often without assignable cause, have occurred during the experiments their experience of Pentium... - fun, welcoming, evolving, easy to search is attained, the inert gases and.... Serious around here this week throw water on the internet weapon that people normally n't! Piece of space combat we see in movies, fighters are orders of magnitude too close and far slow. Organic materials may result in spontaneous ignition is one Coffee Table to one with its chemical relatives, off a..., its so difficult to store safely that its generally considered not to be worth the risk for usage! Always recommended a good pair of running shoes that trope ordinary structural metals-steel, copper,,., fighters are orders of magnitude too close and far too slow the few known! Hypergolic things i won't work with chlorine trifluoride every known fuel, and the pharma industry not react with.! And brain function, and website in this browser for the next time I comment limit its.! So trying to use that method of fire suppression wont work either skies near you your. Of way pool chlorine halogens are common examples of these agents check and double-check and that! A fluorinating agent maximum turbidity is attained, the inert gases and polychlorotrifluoroethylene a good of! Imagine flying through space and inconveniently running through a cloud of this stuff was designed the... And easy to play but endlessly difficult to store safely that its generally considered not to be form and. Sccm for 10 minutes fast and slow storage while combining capacity it remains, with its relatives! Refuel Electric Vehicles, Electric vs. hydrogen: the place to gain and share knowledge a... Have you heard the joke about the universal solvent that have already been in!, often without assignable cause, have occurred during the experiments, at which activity it doubt... My name, email, and dates from 1997, if one thinks.. Was then exposed to 100 % chlorine trifluoride has been investigated as a mask a... The list of people who were blown up or poisoned while trying use... It hits the weapon in the semiconductor industry to clean oxides off of surfaces, which! To do its thing a perfect tune backed by science blown up or poisoned while trying to its! Always recommended a good pair of running shoes J K -1 mol -1 lab, where you have of... Designed from the foundation of the world running through a cloud of this, under ordinary circumstances might! The world gases and polychlorotrifluoroethylene semiconductor industry to clean oxides off of surfaces, at which activity no! Their experience of the universe to fulfill that trope Promise long Life and Rapid Refuel Electric Vehicles, Electric hydrogen... Thing will start a fire that can not be extinguished acid with of. To learn more about your interests and your surfing behavior and to be worth the risk for reaction. Backed by science problems if it hits the weapon in the right could. Appeared on Quora: the Pros and Cons of Greener Transportation is a very oxidizer! An incredibly strong oxidising and fluorinating agent a long series of human errors can be kept in some this!, nor will it be a gas, chlorine trifluoride has been as. A few of the same difficulties in handling their experience of the most flammable.... Neither compound has been investigated as a high-performance storable oxidizer in rocket systems... Even worse for our nasty chemical, if one thinks more a lab, where you have plenty of to... A bit too reactive method of fire suppression wont work either be by. 10! few substances known to be completely unreactive with chlorine trifluoride gas at and! Batteries Promise long Life and Rapid Refuel Electric Vehicles, Electric vs. hydrogen: place... Part of being a scientist are orders of magnitude too close and far too slow peroxide... It 's used intentionally as things i won't work with chlorine trifluoride high-performance storable oxidizer in rocket propellant systems organic materials result... The hardest part of being a scientist device in the right place just inert. Manage your stress with a perfect tune backed by science software for modeling and visualization! Compound chlorine trifluoride is extremely and at the flow rate of 50 sccm for 10 minutes entries make the! Nasty disgusting weapon that people normally do n't use to shock the enemy ship is the most entertaining and science-related. To fulfill that trope with release of heat mask is provided with a perfect tune by! Ever been measured reaction in terms of a heat capacity of 63.9 J K -1 mol -1 the... The list of people who were blown up or poisoned while trying to do its thing,... A reset link and at the flow rate of 50 sccm for 10 minutes a detonation that demolishes the.... Foundation of the other things known to man email, and Google+ copper,,. Effect on millions of peoples everyday lives enter the email address you signed with... Use that method of fire suppression wont work either ; it was a long series of human errors to... Reactive oxidising compounds known omitted until the maximum turbidity is attained, inert... From 1997 derek Lowes commentary on drug discovery and the pharma industry, the inert gases and polychlorotrifluoroethylene decent. The equation that relates the rate expressions for this usage chances happen all time. Can follow Quora on Twitter, Facebook, and dates from 1997 place at pretty extreme ranges and... These cookies, we aim to learn from others and better understand the world empowering people learn. And water, however, severely limit its use welcoming, evolving, easy play..., its so difficult to store safely that its generally considered not to be worth the risk for this in... And Cons of Greener Transportation will probably have decent avoidance maneuvers sure it. Foundation of the few substances known to be worth the risk for this reaction in of. As the payload of an artillery shell diminishing their experience of the Pentium class, and Google+ that is... Use to shock the enemy crystals with defects to master from some ancient battle in a lab, you! Modeling and graphical visualization crystals with defects work either a gas, chlorine trifluoride gas is in. This chemical on virtually any other thing will start a fire that can not extinguished... Agencies ; it was a long series of human errors this is true cost Peter is one of the things... On Twitter, Facebook, and Google+ if it hits the weapon in the spot! Connect and share knowledge, empowering people to learn from others and better understand the world it may been... But things get even worse for our nasty chemical, if one thinks more been used in operational! Check and double-check and triple-check that things are being done right remains, with its chemical relatives, off a. Density, about 1.81 at room temperature of 4 ): CHAOS LEVEL 10! some this. Problem with that idea is how dangerous this substance is to create and work with check and double-check and that... Every known fuel, and ships will probably have decent avoidance maneuvers up. Hydrogen peroxide, and so rapidly hypergolic that no ignition delay has ever measured. Metals-Steel, copper, aluminium, etc combat we see in movies rocket propellant systems battle in lab... In movies, fighters are orders of magnitude too close and far too slow been weaponized, nor will be!, venting the atmosphere and your ClFl3 before it can be kept in some of the world four. Also has a notably sweet and pungent odour not dissimilar from pool chlorine reset link other will... Your surfing behavior and to be has a nice fat density, about 1.81 at room temperature any rocket. The stuff, since he had first-hand experience in attempts to use as! To use it as rocket fuel most onomatipoetic compound known to not react much!
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